TY - JOUR
T1 - A new method for monitoring dediazoniation reactions
T2 - Simultaneous monitoring of concentration and rates of product formation and loss of starting material for the dediazoniation of p-methylbenzenediazonium tetrafluoroborate
AU - Carmen Garcia-Meijide, M.
AU - Bravo-Diaz, C.
AU - Romsted, L. S.
PY - 1998
Y1 - 1998
N2 - We have examined the kinetics and mechanism of the dediazoniation reaction of p-methylbenzenediazonium tetrafluoroborate in the presence and absence of CuCl2 using a methodology developed by us that allows, simultaneously, and within the same experiment to identify, to quantify, and to obtain the rate constants for the formation of all dediazoniation products, and, indirectly, the rate constant for the diazonium salt decomposition. The methodology developed combines the use of coupling reactions, to form a stable azo dye, followed by analysis by HPLC.
AB - We have examined the kinetics and mechanism of the dediazoniation reaction of p-methylbenzenediazonium tetrafluoroborate in the presence and absence of CuCl2 using a methodology developed by us that allows, simultaneously, and within the same experiment to identify, to quantify, and to obtain the rate constants for the formation of all dediazoniation products, and, indirectly, the rate constant for the diazonium salt decomposition. The methodology developed combines the use of coupling reactions, to form a stable azo dye, followed by analysis by HPLC.
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U2 - 10.1002/(sici)1097-4601(1998)30:1
DO - 10.1002/(sici)1097-4601(1998)30:1
M3 - Article
SN - 0538-8066
VL - 30
SP - 31
EP - 39
JO - International Journal of Chemical Kinetics
JF - International Journal of Chemical Kinetics
IS - 1
ER -