An early diagenetic deglacial origin for basal Ediacaran “cap dolostones”

Anne Sofie C. Ahm, Adam C. Maloof, Francis A. Macdonald, Paul F. Hoffman, Christian J. Bjerrum, Uyanga Bold, Catherine V. Rose, Justin V. Strauss, John Andrew Higgins

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The beginning of the Ediacaran Period (∼635 Ma) is marked by conspicuous dolostone units that cap Marinoan glacial deposits worldwide. The extent and sedimentary characteristics of the cap dolostones indicate that anomalous carbonate over-saturation coincided with deglacial sea-level rise and ocean warming. However, the geochemical variability within cap dolostones, both between continents, across single continental margins, and within individual stratigraphic sections has been difficult to reconcile with depositional models. Using a compilation of new calcium and magnesium isotope measurements in Marinoan cap dolostone successions worldwide, we show that the geochemical variability can be explained by early diagenetic dolomitization of aragonite along a spectrum of fluid- and sediment-buffered conditions. Dolostones from the outer platform formed under fluid-buffered conditions, whereas dolostones on the inner platform and foreslope environment formed under sediment-buffered conditions. This spatial pattern of dolomitizing conditions is consistent with buoyant recirculation of glacial seawater within carbonate platforms driven by the deglacial sea-level rise and development of a meltwater surface ocean. Using a numerical diagenetic model to evaluate the geochemical differences between sediment- and fluid-buffered cap dolostone units, we constrain the chemical and isotopic composition of both the dolomitizing fluid (glacial seawater [δ13C ∼ 0–2‰]), the meltwater lens (δ13C ∼−11‰), and the primary aragonite sediment (δ13C ∼−6 to −3‰). These model end-members do not imply that primary geochemical variability did not exist but demonstrates that it is not necessary to change the chemistry of seawater to explain the global stratigraphic variability in the geochemistry of basal Ediacaran cap dolostones. Our results provide a novel framework for understanding the geochemical variability of cap dolostone units, including large excursions in carbon isotopes, and how this variability is the product of local diagenetic processes expressed globally in continental margin environments following the last Snowball Earth.

Original languageEnglish (US)
Pages (from-to)292-307
Number of pages16
JournalEarth and Planetary Science Letters
Volume506
DOIs
StatePublished - Jan 15 2019

Fingerprint

Ediacaran
dolostone
caps
Sediments
Seawater
Fluids
Calcium Carbonate
Carbonates
Sea level
sediments
aragonite
Carbon Isotopes
platforms
fluids
continental shelves
Geochemistry
sea level
fluid
carbonates
Isotopes

All Science Journal Classification (ASJC) codes

  • Geochemistry and Petrology
  • Geophysics
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science

Cite this

Ahm, Anne Sofie C. ; Maloof, Adam C. ; Macdonald, Francis A. ; Hoffman, Paul F. ; Bjerrum, Christian J. ; Bold, Uyanga ; Rose, Catherine V. ; Strauss, Justin V. ; Higgins, John Andrew. / An early diagenetic deglacial origin for basal Ediacaran “cap dolostones”. In: Earth and Planetary Science Letters. 2019 ; Vol. 506. pp. 292-307.
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An early diagenetic deglacial origin for basal Ediacaran “cap dolostones”. / Ahm, Anne Sofie C.; Maloof, Adam C.; Macdonald, Francis A.; Hoffman, Paul F.; Bjerrum, Christian J.; Bold, Uyanga; Rose, Catherine V.; Strauss, Justin V.; Higgins, John Andrew.

In: Earth and Planetary Science Letters, Vol. 506, 15.01.2019, p. 292-307.

Research output: Contribution to journalArticle

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AU - Ahm, Anne Sofie C.

AU - Maloof, Adam C.

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