Cage opening of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 with 2-(aminomethyl)-pyridine: Synthesis and structure of a cobalt salt of functionalized nido-C2B9H10 mono anion

Aderemi R. Oki; Blanca Gilbes; Faina Tarasyuk; Thomas J. Emge

doi:10.1002/aoc.413

Cage opening of 1,2-(CH₂OH)₂-closo-1,2-C₂B₁₀ H₁₀ with 2-(aminomethyl)-pyridine: Synthesis and structure of a cobalt salt of functionalized nido-C₂B₉H₁₀ mono anion

Aderemi R. Oki, Blanca Gilbes, Faina Tarasyuk, Thomas J. Emge

School of Arts and Sciences, Chemistry & Chemical Biology

Rutgers, The State University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The reaction of 1,2-(CH₂OH)₂-closo-1,2-C₂B₁₀ H₁₀ carborane with 2-(aminomethyl)-pyridine in methylene chloride at room temperature led to the partial cage degradation of the closo carborane and its conversion to the nido derivative. The addition of cobalt chloride hexahydrate in methanol to the mixture produced orange crystals 1. The crystal structure of the orange compound has been determined.

Original language	American English
Pages (from-to)	351-355
Number of pages	5
Journal	Applied Organometallic Chemistry
Volume	17
Issue number	6-7
DOIs	https://doi.org/10.1002/aoc.413
State	Published - 2003

ASJC Scopus subject areas

General Chemistry
Inorganic Chemistry

Keywords

2-(aminomethyl)-pyridine
Cage degradation
Cobalt(III)
Nido-carborane
Synthesis
X-ray diffraction analysis

Access to Document

10.1002/aoc.413

Cite this

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title = "Cage opening of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 with 2-(aminomethyl)-pyridine: Synthesis and structure of a cobalt salt of functionalized nido-C2B9H10 mono anion",

abstract = "The reaction of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 carborane with 2-(aminomethyl)-pyridine in methylene chloride at room temperature led to the partial cage degradation of the closo carborane and its conversion to the nido derivative. The addition of cobalt chloride hexahydrate in methanol to the mixture produced orange crystals 1. The crystal structure of the orange compound has been determined.",

keywords = "2-(aminomethyl)-pyridine, Cage degradation, Cobalt(III), Nido-carborane, Synthesis, X-ray diffraction analysis",

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year = "2003",

doi = "10.1002/aoc.413",

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volume = "17",

pages = "351--355",

journal = "Applied Organometallic Chemistry",

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TY - JOUR

T1 - Cage opening of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 with 2-(aminomethyl)-pyridine

T2 - Synthesis and structure of a cobalt salt of functionalized nido-C2B9H10 mono anion

AU - Oki, Aderemi R.

AU - Gilbes, Blanca

AU - Tarasyuk, Faina

AU - Emge, Thomas J.

PY - 2003

Y1 - 2003

N2 - The reaction of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 carborane with 2-(aminomethyl)-pyridine in methylene chloride at room temperature led to the partial cage degradation of the closo carborane and its conversion to the nido derivative. The addition of cobalt chloride hexahydrate in methanol to the mixture produced orange crystals 1. The crystal structure of the orange compound has been determined.

AB - The reaction of 1,2-(CH2OH)2-closo-1,2-C2B10 H10 carborane with 2-(aminomethyl)-pyridine in methylene chloride at room temperature led to the partial cage degradation of the closo carborane and its conversion to the nido derivative. The addition of cobalt chloride hexahydrate in methanol to the mixture produced orange crystals 1. The crystal structure of the orange compound has been determined.

KW - 2-(aminomethyl)-pyridine

KW - Cage degradation

KW - Cobalt(III)

KW - Nido-carborane

KW - Synthesis

KW - X-ray diffraction analysis

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EP - 355

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 6-7

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