The visible spectrum of H3+ is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of H3+ up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein B coefficients. Ab initio predictions for the Einstein B coefficients are obtained from a highly precise dipole moment surface of H3+ and found to be in excellent agreement, even in the region where states have been classified as chaotic.
|Original language||American English|
|Journal||Journal of Chemical Physics|
|State||Published - Dec 28 2014|
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry