Polar oxides are technically of great interest but difficult to prepare. Our recent discoveries predicted that polar oxides can be synthesized in the corundum-derivative A2BB′O6 family with unusually small cations at the A-site and a d0 electron configuration ion at B′-site. When magnetic transition-metal ions are incorporated more interesting polar magnetic oxides can form. In this work we experimentally verified this prediction and prepared LiNbO3 (LN)-type polar magnetic Zn2FeTaO6 via high pressure and temperature synthesis. The crystal structure analysis indicates highly distorted ZnO6 and (Fe/Ta)O6 octahedra, and an estimated spontaneous polarization (PS) of ∼50 μC/cm2 along the c-axis was obtained from point charge model calculations. Zn2Fe3+Ta 5+O6 has a lower magnetic transition temperature (T N ∼ 22 K) than the Mn2FeTaO6 analogue but is less conductive. The dielectric and polarization measurements indicate a potentially switchable component.
|Original language||American English|
|Number of pages||4|
|Journal||Journal of the American Chemical Society|
|State||Published - Jun 18 2014|
ASJC Scopus subject areas
- Colloid and Surface Chemistry