Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The reaction pathway through which YBa2Cu3O6+x (123) is formed from a precursor material containing finely mixed Y2O3, BaCO3 and CuO prepared by a spray pyrolysis process has been studied. The precursor powder was loosely packed in cylindrical crucibles and heated for different lengths of time in N2 and in O2 at different temperatures and pressures. The samples were then layered and analyzed by XRD to assess the spatial variations in the composition. The tetragonal 123 phase was the primary reaction product that could be identified by XRD. At 700-750°C and atmospheric pressure, the formation of the 123 phase was found to occur at first in the outer layer of the packing and subsequently this front moved into the specimen, in both N2 and O2 environments. Experiments carried out at lower pressures revealed that a decrease in pressure resulted in an enhancement in the conversion. Similar trends were obtained with dry-pressed compacts of the precursor as well. This shows clearly that the rate of removal of CO2 from the interior of the sample affects the progress of these reactions in a profound way. Two binary mixtures 2BaCO3 + 3CuO and 4BaCO3 + Y2O3 corresponding to the stoichimetry as in the 123 compound were prepared by a spray pyrolysis technique. Thermogravimetric analysis of these binary mixtures and the precursor for 123 revealed that the rate-limiting step in the formation of 123 is the reaction between BaCO3 and CuO.

Original languageEnglish (US)
Title of host publicationAIChE Symposium Series
EditorsThomas O. Mensah
PublisherPubl by AIChE
Pages82-87
Number of pages6
Volume88
Edition287
ISBN (Print)0816905673
StatePublished - Dec 1 1992

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Spray pyrolysis
Binary mixtures
Crucibles
Reaction products
Powders
Atmospheric pressure
Thermogravimetric analysis
Chemical analysis
Experiments
Temperature

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Sundaresan, S. (1992). Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO. In T. O. Mensah (Ed.), AIChE Symposium Series (287 ed., Vol. 88, pp. 82-87). Publ by AIChE.
Sundaresan, Sankaran. / Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO. AIChE Symposium Series. editor / Thomas O. Mensah. Vol. 88 287. ed. Publ by AIChE, 1992. pp. 82-87
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Sundaresan, S 1992, Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO. in TO Mensah (ed.), AIChE Symposium Series. 287 edn, vol. 88, Publ by AIChE, pp. 82-87.

Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO. / Sundaresan, Sankaran.

AIChE Symposium Series. ed. / Thomas O. Mensah. Vol. 88 287. ed. Publ by AIChE, 1992. p. 82-87.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - The reaction pathway through which YBa2Cu3O6+x (123) is formed from a precursor material containing finely mixed Y2O3, BaCO3 and CuO prepared by a spray pyrolysis process has been studied. The precursor powder was loosely packed in cylindrical crucibles and heated for different lengths of time in N2 and in O2 at different temperatures and pressures. The samples were then layered and analyzed by XRD to assess the spatial variations in the composition. The tetragonal 123 phase was the primary reaction product that could be identified by XRD. At 700-750°C and atmospheric pressure, the formation of the 123 phase was found to occur at first in the outer layer of the packing and subsequently this front moved into the specimen, in both N2 and O2 environments. Experiments carried out at lower pressures revealed that a decrease in pressure resulted in an enhancement in the conversion. Similar trends were obtained with dry-pressed compacts of the precursor as well. This shows clearly that the rate of removal of CO2 from the interior of the sample affects the progress of these reactions in a profound way. Two binary mixtures 2BaCO3 + 3CuO and 4BaCO3 + Y2O3 corresponding to the stoichimetry as in the 123 compound were prepared by a spray pyrolysis technique. Thermogravimetric analysis of these binary mixtures and the precursor for 123 revealed that the rate-limiting step in the formation of 123 is the reaction between BaCO3 and CuO.

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Sundaresan S. Effect of ambient environment and pressure on the formation of YBa2Cu3O6+x from Y2O3, BaCO3 and CuO. In Mensah TO, editor, AIChE Symposium Series. 287 ed. Vol. 88. Publ by AIChE. 1992. p. 82-87