Functionalized carbon nanotube immobilized membrane for low temperature ammonia removal via membrane distillation

Worawit Intrchom, Sagar Roy, Somenath Mitra

Research output: Contribution to journalArticle

Abstract

Enhanced ammonia separation via direct contact membrane distillation (DCMD) using carbon nanotube immobilized membranes (CNIMs) is presented. The CNIMs were prepared using raw carbon nanotubes (CNTs) as well as more polar carboxylated carbon nanotubes referred to as f-CNTs. The ammonia removal by both CNIMs were markedly superior to that of the original PTFE membrane, while functionalized CNIM (CNIM-f) showed the best performance in terms of flux, mass transfer coefficients and selectivity. The flux with f-CNTs was 63% higher than the PTFE membrane and 22% higher than raw CNTs. Similar trends were observed for ammonia removal efficiency and mass transfer coefficients that were also significantly higher for the f-CNTs. The ammonia selectivity with respect to water vapor decreased with temperature for the PTFE and CNIM with raw CNTs, but in the presence of f-CNTs the selectivity did not show any decrease with temperature. The enhancement in ammonia removal with f-CNTs is attributed to the favored chemisorption of ammonia on the f-CNTs which was evident from contact angle measurements that showed a dramatic decrease for aqueous ammonia in the presence of the carboxylic groups.

Original languageEnglish (US)
Article number116188
JournalSeparation and Purification Technology
Volume235
DOIs
StatePublished - Mar 18 2020

Fingerprint

Carbon Nanotubes
Ammonia
Distillation
Carbon nanotubes
Membranes
Temperature
Polytetrafluoroethylene
Polytetrafluoroethylenes
Mass transfer
Fluxes
Steam
Angle measurement
Chemisorption

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Filtration and Separation

Keywords

  • Ammonia separation
  • Carbon nanotube immobilized membranes (CNIMs)
  • Direct contact membrane distillation (DCMD)
  • Flux enhancement

Cite this

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title = "Functionalized carbon nanotube immobilized membrane for low temperature ammonia removal via membrane distillation",
abstract = "Enhanced ammonia separation via direct contact membrane distillation (DCMD) using carbon nanotube immobilized membranes (CNIMs) is presented. The CNIMs were prepared using raw carbon nanotubes (CNTs) as well as more polar carboxylated carbon nanotubes referred to as f-CNTs. The ammonia removal by both CNIMs were markedly superior to that of the original PTFE membrane, while functionalized CNIM (CNIM-f) showed the best performance in terms of flux, mass transfer coefficients and selectivity. The flux with f-CNTs was 63{\%} higher than the PTFE membrane and 22{\%} higher than raw CNTs. Similar trends were observed for ammonia removal efficiency and mass transfer coefficients that were also significantly higher for the f-CNTs. The ammonia selectivity with respect to water vapor decreased with temperature for the PTFE and CNIM with raw CNTs, but in the presence of f-CNTs the selectivity did not show any decrease with temperature. The enhancement in ammonia removal with f-CNTs is attributed to the favored chemisorption of ammonia on the f-CNTs which was evident from contact angle measurements that showed a dramatic decrease for aqueous ammonia in the presence of the carboxylic groups.",
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author = "Worawit Intrchom and Sagar Roy and Somenath Mitra",
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AU - Intrchom, Worawit

AU - Roy, Sagar

AU - Mitra, Somenath

PY - 2020/3/18

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N2 - Enhanced ammonia separation via direct contact membrane distillation (DCMD) using carbon nanotube immobilized membranes (CNIMs) is presented. The CNIMs were prepared using raw carbon nanotubes (CNTs) as well as more polar carboxylated carbon nanotubes referred to as f-CNTs. The ammonia removal by both CNIMs were markedly superior to that of the original PTFE membrane, while functionalized CNIM (CNIM-f) showed the best performance in terms of flux, mass transfer coefficients and selectivity. The flux with f-CNTs was 63% higher than the PTFE membrane and 22% higher than raw CNTs. Similar trends were observed for ammonia removal efficiency and mass transfer coefficients that were also significantly higher for the f-CNTs. The ammonia selectivity with respect to water vapor decreased with temperature for the PTFE and CNIM with raw CNTs, but in the presence of f-CNTs the selectivity did not show any decrease with temperature. The enhancement in ammonia removal with f-CNTs is attributed to the favored chemisorption of ammonia on the f-CNTs which was evident from contact angle measurements that showed a dramatic decrease for aqueous ammonia in the presence of the carboxylic groups.

AB - Enhanced ammonia separation via direct contact membrane distillation (DCMD) using carbon nanotube immobilized membranes (CNIMs) is presented. The CNIMs were prepared using raw carbon nanotubes (CNTs) as well as more polar carboxylated carbon nanotubes referred to as f-CNTs. The ammonia removal by both CNIMs were markedly superior to that of the original PTFE membrane, while functionalized CNIM (CNIM-f) showed the best performance in terms of flux, mass transfer coefficients and selectivity. The flux with f-CNTs was 63% higher than the PTFE membrane and 22% higher than raw CNTs. Similar trends were observed for ammonia removal efficiency and mass transfer coefficients that were also significantly higher for the f-CNTs. The ammonia selectivity with respect to water vapor decreased with temperature for the PTFE and CNIM with raw CNTs, but in the presence of f-CNTs the selectivity did not show any decrease with temperature. The enhancement in ammonia removal with f-CNTs is attributed to the favored chemisorption of ammonia on the f-CNTs which was evident from contact angle measurements that showed a dramatic decrease for aqueous ammonia in the presence of the carboxylic groups.

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KW - Direct contact membrane distillation (DCMD)

KW - Flux enhancement

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