Intramolecular amino delivery reactions for the synthesis of valienamine and analogues

Spencer Knapp, Andrew B.J. Naughton, T. G. Murali Dhar

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

Iodocyclization and [3,3] sigmatropic rearrangement reactions of N-substituted carbonimidothioates are used to prepare valienamine (1), 7-nor-valienamine (8), and the valienamine-based pseudo-disaccharide 12.

Original languageEnglish (US)
Pages (from-to)1025-1028
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number8
DOIs
StatePublished - Feb 18 1992

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Keywords

  • [3,3] rearrangement
  • carbonimidothioates
  • glucosidase inhibitors
  • iodocyclization
  • pseudo-disaccharides

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