Low-Loss Tunable Infrared Plasmons in the High-Mobility Perovskite (Ba,La)SnO3

Hongbin Yang, Andrea Konečná, Xianghan Xu, Sang-Wook Cheong, Eric Garfunkel, F. Javier García de Abajo, Philip Batson

Research output: Contribution to journalArticlepeer-review

Abstract

BaSnO3 exhibits the highest carrier mobility among perovskite oxides, making it ideal for oxide electronics. Collective charge carrier oscillations known as plasmons are expected to arise in this material, thus providing a tool to control the nanoscale optical field for optoelectronics applications. Here, the existence of relatively long-lived plasmons supported by high-mobility charge carriers in La-doped BaSnO3 (BLSO) is demonstrated. By exploiting the high spatial and energy resolution of electron energy-loss spectroscopy with a focused beam in a scanning transmission electron microscope, the dispersion, confinement ratio, and damping of infrared localized surface plasmons (LSPs) in BLSO nanoparticles are systematically investigated. It is found that LSPs in BLSO exhibit a high degree of spatial confinement compared to those sustained by noble metals and have relatively low losses and high quality factors with respect to other doped oxides. Further analysis clarifies the relation between plasmon damping and carrier mobility in BLSO. The results support the use of nanostructured degenerate semiconductors for plasmonic applications in the infrared region and establish a solid alternative to more traditional plasmonic materials.

Original languageEnglish (US)
Article number2106897
JournalSmall
Volume18
Issue number16
DOIs
StatePublished - Apr 21 2022

ASJC Scopus subject areas

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

Keywords

  • monochromated electron energy-loss spectroscopy (EELS)
  • perovskite oxide
  • STEM-electron energy-loss spectroscopy (EELS)
  • surface plasmons
  • transparent conducting oxides

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