Mn2CoReO6 a robust multisublattice antiferromagnetic perovskite with small A-site cations

Corey E. Frank, Emma E. McCabe, Fabio Orlandi, Pascal Manuel, Xiaoyan Tan, Zheng Deng, Mark Croft, Vanessa Cascos, Thomas Emge, Hai L. Feng, Saul Lapidus, Changqing Jin, Meixia Wu, Man Rong Li, Steven Ehrlich, Syed Khalid, Nicholas Quackenbush, Shuang Yu, David Walker, Martha Greenblatt

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8 Scopus citations

Abstract

Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.

Original languageEnglish (US)
Pages (from-to)3331-3334
Number of pages4
JournalChemical Communications
Volume55
Issue number23
DOIs
StatePublished - 2019

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Chemistry(all)
  • Catalysis

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