OVERESTIMATION OF THE RATE CONSTANT OF THE Cl plus SiH//4 REACTION DETERMINED UNDER FLOW CONDITIONS DUE TO HETEROGENEOUS PROCESSES.

V. R. Braun, A. I. Chichinin, L. N. Krasnoperov

Research output: Contribution to journalArticlepeer-review

Abstract

The rate constant of the Cl plus SiH//4 reaction has been measured by laser magnetic resonance under flow conditions. An anomalously high value left bracket (4. 5 plus or minus 1. 7) multiplied by (times) 10** minus **1**0 cm**3/sec right bracket has been obtained. It has been shown that the overestimation of the rate constant of this reaction is caused by heterogeneous processes.

Original languageEnglish (US)
Pages (from-to)392-398
Number of pages7
JournalKinetics and Catalysis
Volume26
Issue numberpt 2
StatePublished - Mar 1 1985
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis
  • Computer Science Applications
  • Modeling and Simulation

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