Pronounced sponge-like nanostructure in propylammonium nitrate

Robert Hayes, Silvia Imberti, Gregory G. Warr, Rob Atkin

Research output: Contribution to journalArticle

139 Scopus citations

Abstract

The bulk structure of the ionic liquid propylammonium nitrate (PAN) has been determined using neutron diffraction. Empirical potential structure refinement (EPSR) fits to the data show that PAN self-assembles into a quasi-periodic bicontinuous nanostructure reminiscent of an amphiphile L 3-sponge phase. Atomic detail on the ion arrangements around the propylammonium cation and nitrate anion yields evidence of hydrogen bonding between ammonium and nitrate groups and of strong alkyl chain aggregation and interdigitation. The resultant amphiphilic PAN nanostructure is more pronounced than that previously determined for ethylammonium nitrate (EAN) or ethanolammonium nitrate (EtAN).

Original languageEnglish (US)
Pages (from-to)13544-13551
Number of pages8
JournalPhysical Chemistry Chemical Physics
Volume13
Issue number30
DOIs
StatePublished - Aug 14 2011

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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