Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases

Marcin H. Kudzin; Józef Drabowicz; Frank Jordan; Zbigniew H. Kudzin; Paweł Urbaniak

doi:10.1080/10426507.2018.1540002

Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases

Marcin H. Kudzin
, Józef Drabowicz
, Frank Jordan
, Zbigniew H. Kudzin
, Paweł Urbaniak

Rutgers Newark, Chemistry

Rutgers, The State University

Research output: Contribution to journal › Article › peer-review

Abstract

The stability of the representative series of ω-aminoalkylphosphonic acids (ω-AA^P: 2-Ala^P and 3-Ala^P), 1-aminoalkylphosphonic acids (AA^P: Gly^P; Ala^P and Pgl^P) and quaternary 1-aminoalkylphosphonic acids (AA^P: Mal^P), 1-(N-alkylamino)alkylphosphonic acids (R-AA^P: tBu-Gly^P; tBu-Ala^P; Me-Hal^P; Et-Hal^P and Et-Mal^P) and 1-(N,N-dialkylamino)alkylphosphonic acids (R₂-AA^P: Me₂-Gly^P and Me₂-Hal^P) being exposed to acidic (2 M H₂SO₄) and/or basic (2 M KOH) solutions in the temperature range of 25-100 °C, was investigated.

Original language	American English
Pages (from-to)	326-328
Number of pages	3
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	194
Issue number	4-6
DOIs	https://doi.org/10.1080/10426507.2018.1540002
State	Published - May 27 2019

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

Keywords

Aminoalkylphosphonic acids
degradation
hydrolytic stability

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10.1080/10426507.2018.1540002

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title = "Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases",

abstract = "The stability of the representative series of ω-aminoalkylphosphonic acids (ω-AAP: 2-AlaP and 3-AlaP), 1-aminoalkylphosphonic acids (AAP: GlyP; AlaP and PglP) and quaternary 1-aminoalkylphosphonic acids (AAP: MalP), 1-(N-alkylamino)alkylphosphonic acids (R-AAP: tBu-GlyP; tBu-AlaP; Me-HalP; Et-HalP and Et-MalP) and 1-(N,N-dialkylamino)alkylphosphonic acids (R2-AAP: Me2-GlyP and Me2-HalP) being exposed to acidic (2 M H2SO4) and/or basic (2 M KOH) solutions in the temperature range of 25-100 °C, was investigated.",

keywords = "Aminoalkylphosphonic acids, degradation, hydrolytic stability",

author = "Kudzin, \{Marcin H.\} and J{\'o}zef Drabowicz and Frank Jordan and Kudzin, \{Zbigniew H.\} and Pawe{\l} Urbaniak",

note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Taylor \& Francis Group, LLC.",

year = "2019",

month = may,

day = "27",

doi = "10.1080/10426507.2018.1540002",

language = "American English",

volume = "194",

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journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

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TY - JOUR

T1 - Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases

AU - Kudzin, Marcin H.

AU - Drabowicz, Józef

AU - Jordan, Frank

AU - Kudzin, Zbigniew H.

AU - Urbaniak, Paweł

PY - 2019/5/27

Y1 - 2019/5/27

N2 - The stability of the representative series of ω-aminoalkylphosphonic acids (ω-AAP: 2-AlaP and 3-AlaP), 1-aminoalkylphosphonic acids (AAP: GlyP; AlaP and PglP) and quaternary 1-aminoalkylphosphonic acids (AAP: MalP), 1-(N-alkylamino)alkylphosphonic acids (R-AAP: tBu-GlyP; tBu-AlaP; Me-HalP; Et-HalP and Et-MalP) and 1-(N,N-dialkylamino)alkylphosphonic acids (R2-AAP: Me2-GlyP and Me2-HalP) being exposed to acidic (2 M H2SO4) and/or basic (2 M KOH) solutions in the temperature range of 25-100 °C, was investigated.

AB - The stability of the representative series of ω-aminoalkylphosphonic acids (ω-AAP: 2-AlaP and 3-AlaP), 1-aminoalkylphosphonic acids (AAP: GlyP; AlaP and PglP) and quaternary 1-aminoalkylphosphonic acids (AAP: MalP), 1-(N-alkylamino)alkylphosphonic acids (R-AAP: tBu-GlyP; tBu-AlaP; Me-HalP; Et-HalP and Et-MalP) and 1-(N,N-dialkylamino)alkylphosphonic acids (R2-AAP: Me2-GlyP and Me2-HalP) being exposed to acidic (2 M H2SO4) and/or basic (2 M KOH) solutions in the temperature range of 25-100 °C, was investigated.

KW - Aminoalkylphosphonic acids

KW - degradation

KW - hydrolytic stability

UR - https://www.scopus.com/pages/publications/85067292649

UR - https://www.scopus.com/pages/publications/85067292649#tab=citedBy

U2 - 10.1080/10426507.2018.1540002

DO - 10.1080/10426507.2018.1540002

M3 - Article

SN - 1042-6507

VL - 194

SP - 326

EP - 328

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 4-6

ER -

Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases

Abstract

ASJC Scopus subject areas

Keywords

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