Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal-Organic Frameworks

Jincheng Si; Hai Lun Xia; Kang Zhou; Jingbai Li; Kai Xing; Jiafeng Miao; Jian Zhang; Hao Wang; Lu Lu Qu; Xiao Yuan Liu; Jing Li

doi:10.1021/jacs.2c09832

Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal-Organic Frameworks

Jincheng Si, Hai Lun Xia, Kang Zhou, Jingbai Li, Kai Xing, Jiafeng Miao, Jian Zhang, Hao Wang, Lu Lu Qu, Xiao Yuan Liu, Jing Li

Research output: Contribution to journal › Article › peer-review

Abstract

Herein, we demonstrate the successful utilization of reticular chemistry as an excellent designing strategy for the deliberate construction of a zirconium-tetracarboxylate metal-organic framework (MOF) inspired by the Olympic rings. HIAM-4017, with an unprecedented (4,8)-c underlying net topology termed jcs, was developed via insightful reconstruction of the rings and judicious design of a nonsymmetric organic linker. HIAM-4017 exhibits high porosity and excellent chemical and thermal stability. Furthermore, excited-state intramolecular proton transfer (ESIPT) was achieved in an isoreticular MOF, HIAM-4018, with a large Stokes shift of 155 nm as a result of introducing the hydroxyl group to the linker skeleton to induce OH···N interactions. Such interactions were analyzed thoroughly by employing the time-dependent density functional theory (TD-DFT). Because of their good thermal and chemical stability, and strong luminescence, nanosized HIAM-4017 and HIAM-4018 were fabricated and used for Cr2O72- detection. Both MOFs demonstrate excellent sensitivity and selectivity. This work represents a neat example of building structure- and property-specific MOFs guided by reticular chemistry.

Original language	English (US)
Pages (from-to)	22170-22177
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	144
Issue number	48
DOIs	https://doi.org/10.1021/jacs.2c09832
State	Published - Dec 7 2022
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.2c09832

Cite this

@article{485eddc79f3c469fb7dee83cc25e4bd9,

title = "Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal-Organic Frameworks",

abstract = "Herein, we demonstrate the successful utilization of reticular chemistry as an excellent designing strategy for the deliberate construction of a zirconium-tetracarboxylate metal-organic framework (MOF) inspired by the Olympic rings. HIAM-4017, with an unprecedented (4,8)-c underlying net topology termed jcs, was developed via insightful reconstruction of the rings and judicious design of a nonsymmetric organic linker. HIAM-4017 exhibits high porosity and excellent chemical and thermal stability. Furthermore, excited-state intramolecular proton transfer (ESIPT) was achieved in an isoreticular MOF, HIAM-4018, with a large Stokes shift of 155 nm as a result of introducing the hydroxyl group to the linker skeleton to induce OH···N interactions. Such interactions were analyzed thoroughly by employing the time-dependent density functional theory (TD-DFT). Because of their good thermal and chemical stability, and strong luminescence, nanosized HIAM-4017 and HIAM-4018 were fabricated and used for Cr2O72- detection. Both MOFs demonstrate excellent sensitivity and selectivity. This work represents a neat example of building structure- and property-specific MOFs guided by reticular chemistry.",

author = "Jincheng Si and Xia, {Hai Lun} and Kang Zhou and Jingbai Li and Kai Xing and Jiafeng Miao and Jian Zhang and Hao Wang and Qu, {Lu Lu} and Liu, {Xiao Yuan} and Jing Li",

note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",

year = "2022",

month = dec,

day = "7",

doi = "10.1021/jacs.2c09832",

language = "English (US)",

volume = "144",

pages = "22170--22177",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "48",

}

TY - JOUR

T1 - Reticular Chemistry with Art

T2 - A Case Study of Olympic Rings-Inspired Metal-Organic Frameworks

AU - Si, Jincheng

AU - Xia, Hai Lun

AU - Zhou, Kang

AU - Li, Jingbai

AU - Xing, Kai

AU - Miao, Jiafeng

AU - Zhang, Jian

AU - Wang, Hao

AU - Qu, Lu Lu

AU - Liu, Xiao Yuan

AU - Li, Jing

PY - 2022/12/7

Y1 - 2022/12/7

N2 - Herein, we demonstrate the successful utilization of reticular chemistry as an excellent designing strategy for the deliberate construction of a zirconium-tetracarboxylate metal-organic framework (MOF) inspired by the Olympic rings. HIAM-4017, with an unprecedented (4,8)-c underlying net topology termed jcs, was developed via insightful reconstruction of the rings and judicious design of a nonsymmetric organic linker. HIAM-4017 exhibits high porosity and excellent chemical and thermal stability. Furthermore, excited-state intramolecular proton transfer (ESIPT) was achieved in an isoreticular MOF, HIAM-4018, with a large Stokes shift of 155 nm as a result of introducing the hydroxyl group to the linker skeleton to induce OH···N interactions. Such interactions were analyzed thoroughly by employing the time-dependent density functional theory (TD-DFT). Because of their good thermal and chemical stability, and strong luminescence, nanosized HIAM-4017 and HIAM-4018 were fabricated and used for Cr2O72- detection. Both MOFs demonstrate excellent sensitivity and selectivity. This work represents a neat example of building structure- and property-specific MOFs guided by reticular chemistry.

AB - Herein, we demonstrate the successful utilization of reticular chemistry as an excellent designing strategy for the deliberate construction of a zirconium-tetracarboxylate metal-organic framework (MOF) inspired by the Olympic rings. HIAM-4017, with an unprecedented (4,8)-c underlying net topology termed jcs, was developed via insightful reconstruction of the rings and judicious design of a nonsymmetric organic linker. HIAM-4017 exhibits high porosity and excellent chemical and thermal stability. Furthermore, excited-state intramolecular proton transfer (ESIPT) was achieved in an isoreticular MOF, HIAM-4018, with a large Stokes shift of 155 nm as a result of introducing the hydroxyl group to the linker skeleton to induce OH···N interactions. Such interactions were analyzed thoroughly by employing the time-dependent density functional theory (TD-DFT). Because of their good thermal and chemical stability, and strong luminescence, nanosized HIAM-4017 and HIAM-4018 were fabricated and used for Cr2O72- detection. Both MOFs demonstrate excellent sensitivity and selectivity. This work represents a neat example of building structure- and property-specific MOFs guided by reticular chemistry.

UR - http://www.scopus.com/inward/record.url?scp=85143085441&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85143085441&partnerID=8YFLogxK

U2 - 10.1021/jacs.2c09832

DO - 10.1021/jacs.2c09832

M3 - Article

C2 - 36416791

SN - 0002-7863

VL - 144

SP - 22170

EP - 22177

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 48

ER -

Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal-Organic Frameworks

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this