Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp³)-H Cross-Coupling

Keyphrases

• Cross-coupling 100%
• Mechanistic Implication 100%
• Photoredox 100%
• Chlorine 100%
• C(sp3)-H 100%
• Photoelimination 100%
• Ni(II) 42%
• Aryl Chlorides 42%
• Chlorine Radical 42%
• Nickel Catalyst 28%
• Cross-coupling Reaction 28%
• Aryl Halides 28%
• Photochemistry 28%
• Photoredox Catalysis 28%
• Hydrogen Atom Transfer 28%
• Alkyl Radicals 28%
• Chlorine Atom 28%
• One-electron Oxidation 28%
• Ni(III) 28%
• Photoredox Catalyst 28%
• C(sp3)-H Bond 28%
• Triethyl Orthoformate 28%
• Mechanistic Understanding 14%
• Radical Formation 14%
• Operative 14%
• Mechanistic Investigation 14%
• Two-photon 14%
• Active Research 14%
• Alkanes 14%
• Ether 14%
• Photolysis 14%
• Energy Transfer 14%
• Methylation Reaction 14%
• Photophysics 14%
• Electron Transfer 14%
• New Catalysts 14%
• Toluene 14%
• Catalyst Design 14%
• Oxidation State 14%
• Synthetic Organic Chemistry 14%
• Photoinduced 14%
• Scission 14%
• Chloride 14%
• Synthetic Transformation 14%
• New Synthetic Method 14%
• Nickel Catalysis 14%
• Charge Transfer States 14%
• One-electron Reduction 14%
• Methyl Radical 14%
• Radical Generation 14%
• Ni Catalyst 14%
• Visible-light-driven 14%
• Drive Mechanism 14%
• Site-selective 14%
• Photoredox Reaction 14%
• Catalytic Generation 14%
• Chloroformates 14%
• Oxidation Studies 14%
• Complex Commons 14%
• Halide Complexes 14%
• Metallaphotoredox 14%
• 1,3-dioxolane 14%
• Photoredox-catalyzed 14%
• Functionalization Methods 14%
• Formylation 14%
• Light Reactions 14%
• Emission Quenching 14%
• Redox-neutral Process 14%
• Organometallic Ni Complexes 14%
• Cross-coupling Catalysts 14%
• C(sp3)-H Arylation 14%
• Sequential Capture 14%
• C(sp3)-H Functionalization 14%

Chemistry

• Photoredox 100%
• Halide 40%
• Cross-Coupling Reaction 40%
• Photoredox Catalysis 40%
• Hydrogen Atom 40%
• Chlorine Atom 40%
• Photochemical Reaction 40%
• Photophysics 20%
• Organic Chemistry 20%
• Metallocene 20%
• Catalyst Design 20%
• Photolysis 20%
• Energy Transfer 20%
• Nickel Catalysis 20%
• Arylation 20%
• Charge Transfer State 20%
• Formylation 20%
• 1,3-dioxolane 20%
• formation 20%
• methylation 20%
• Alkane 20%
• Visible Spectrum 20%
• Cleavage 20%