Tailoring polymeric hydrogels through cyclodextrin host-guest complexation

Xuhong Guo, Jie Wang, Li Li, Duc Truc Pham, Philip Clements, Stephen F. Lincoln, Bruce L. May, Oingchuan Chen, Li Zheng, Robert Krafft Prud'homme

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

A close correlation between molecular-level interactions and macroscopic characteristics of polymer networks exists. The characteristics of the polymeric hydrogels assembled from β-cyclodextrin (β-CD) and adamantyl (AD) substituted poly(acrylate)s can be tailored through selective host-guest complexation between β-CD and AD substituents and their tethers. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric inter-strand linkage in polymer network formation. This understanding of the factors involved in polymeric hydrogel formation points the way towards the construction of increasingly sophisticated biocompatible materials. (Figure Presented)

Original languageEnglish (US)
Pages (from-to)300-304
Number of pages5
JournalMacromolecular Rapid Communications
Volume31
Issue number3
DOIs
StatePublished - Feb 2 2010

Fingerprint

Hydrogels
Cyclodextrins
Complexation
Polymers
Hydrogel
Biocompatible Materials
Biomaterials
acrylic acid

All Science Journal Classification (ASJC) codes

  • Materials Chemistry
  • Polymers and Plastics
  • Organic Chemistry

Cite this

Guo, Xuhong ; Wang, Jie ; Li, Li ; Pham, Duc Truc ; Clements, Philip ; Lincoln, Stephen F. ; May, Bruce L. ; Chen, Oingchuan ; Zheng, Li ; Prud'homme, Robert Krafft. / Tailoring polymeric hydrogels through cyclodextrin host-guest complexation. In: Macromolecular Rapid Communications. 2010 ; Vol. 31, No. 3. pp. 300-304.
@article{0bdec98329714d17b616fcc9eca54675,
title = "Tailoring polymeric hydrogels through cyclodextrin host-guest complexation",
abstract = "A close correlation between molecular-level interactions and macroscopic characteristics of polymer networks exists. The characteristics of the polymeric hydrogels assembled from β-cyclodextrin (β-CD) and adamantyl (AD) substituted poly(acrylate)s can be tailored through selective host-guest complexation between β-CD and AD substituents and their tethers. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric inter-strand linkage in polymer network formation. This understanding of the factors involved in polymeric hydrogel formation points the way towards the construction of increasingly sophisticated biocompatible materials. (Figure Presented)",
author = "Xuhong Guo and Jie Wang and Li Li and Pham, {Duc Truc} and Philip Clements and Lincoln, {Stephen F.} and May, {Bruce L.} and Oingchuan Chen and Li Zheng and Prud'homme, {Robert Krafft}",
year = "2010",
month = "2",
day = "2",
doi = "https://doi.org/10.1002/marc.200900560",
language = "English (US)",
volume = "31",
pages = "300--304",
journal = "Macromolecular Rapid Communications",
issn = "1022-1336",
publisher = "Wiley-VCH Verlag",
number = "3",

}

Guo, X, Wang, J, Li, L, Pham, DT, Clements, P, Lincoln, SF, May, BL, Chen, O, Zheng, L & Prud'homme, RK 2010, 'Tailoring polymeric hydrogels through cyclodextrin host-guest complexation', Macromolecular Rapid Communications, vol. 31, no. 3, pp. 300-304. https://doi.org/10.1002/marc.200900560

Tailoring polymeric hydrogels through cyclodextrin host-guest complexation. / Guo, Xuhong; Wang, Jie; Li, Li; Pham, Duc Truc; Clements, Philip; Lincoln, Stephen F.; May, Bruce L.; Chen, Oingchuan; Zheng, Li; Prud'homme, Robert Krafft.

In: Macromolecular Rapid Communications, Vol. 31, No. 3, 02.02.2010, p. 300-304.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Tailoring polymeric hydrogels through cyclodextrin host-guest complexation

AU - Guo, Xuhong

AU - Wang, Jie

AU - Li, Li

AU - Pham, Duc Truc

AU - Clements, Philip

AU - Lincoln, Stephen F.

AU - May, Bruce L.

AU - Chen, Oingchuan

AU - Zheng, Li

AU - Prud'homme, Robert Krafft

PY - 2010/2/2

Y1 - 2010/2/2

N2 - A close correlation between molecular-level interactions and macroscopic characteristics of polymer networks exists. The characteristics of the polymeric hydrogels assembled from β-cyclodextrin (β-CD) and adamantyl (AD) substituted poly(acrylate)s can be tailored through selective host-guest complexation between β-CD and AD substituents and their tethers. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric inter-strand linkage in polymer network formation. This understanding of the factors involved in polymeric hydrogel formation points the way towards the construction of increasingly sophisticated biocompatible materials. (Figure Presented)

AB - A close correlation between molecular-level interactions and macroscopic characteristics of polymer networks exists. The characteristics of the polymeric hydrogels assembled from β-cyclodextrin (β-CD) and adamantyl (AD) substituted poly(acrylate)s can be tailored through selective host-guest complexation between β-CD and AD substituents and their tethers. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric inter-strand linkage in polymer network formation. This understanding of the factors involved in polymeric hydrogel formation points the way towards the construction of increasingly sophisticated biocompatible materials. (Figure Presented)

UR - http://www.scopus.com/inward/record.url?scp=75749138550&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=75749138550&partnerID=8YFLogxK

U2 - https://doi.org/10.1002/marc.200900560

DO - https://doi.org/10.1002/marc.200900560

M3 - Article

VL - 31

SP - 300

EP - 304

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

SN - 1022-1336

IS - 3

ER -